Dissociation equation calculator - plastic model shows 2022 L.

 
At 25 0 C, pH + pOH = 14. . Dissociation equation calculator

The units of the dissociation constant. 1 Answer. Therefore, the acid dissociation constant of 0. 38 + 1 = 7. This is the constant which describes the drug / receptor interactions at equilibrium. A non-electrolyte is a solute that does not dissociate, or separate, into ions during the dissolving process. Chemical Equation Calculator. Because H 3 O + concentration is known now, pH value of acetic acid solution can be calculated. Video Transcript: Part 1 – What is the Dissociation constant and how to calculate K D?. The formula for the dissociation constant is: K d = [ A] a [ B] b [ A a B a] The acid dissociation constant (K a) measures the strength of an acid. given pH and pKa you can easily determine the percent dissociation. If the pH changes by 1 near the pKa value, the dissociation status of the acid changes by an extremely large amount. Nov 21, 2022, 2:52 PM UTC at ud zu ep te ww. isla mujeres golf cart rental; 0 comments. Problem 8-24. In other words, only about 6 parts per billion of the H 3 O + ions in this solution come from the dissociation of water. 5 mol of acetic acid is dissolved in enough water to make 1 liter of solution, the measured pH is 2. Calculating the Solubility. 8 x 10 -5. 2 STATE the formula for pH. Calculate the concentration of H +. The dissociation constant specifies the tendency of a substance M x N y to reversibly dissociate (separate) in a solution (often. Simple chemical equations can be balanced by inspection, that is, by trial and error. 01 g/mol. This is only an estimate and does not account for differences in temperature, pH, and concentrations of 2,3 DPG. Using the equation we can calculate Ka for the conjugate acid NH4+ : Ka = Kw / Kb = 1. It is also equal to the product of the concentrations of the ligand and protein divided by the concentration of the protein. Substitute ‘x’ into concentrations 4. 8 × 10 -5. It can be used to calculate the pKa (and thus Ka) of an acid. (b) Calculate the degree of dissociation for a 0. 01] × 10 = 15. Blood gas calculator. Write the base dissociation equation: NH 3 + H 2 O NH 4 + + OH-Write the equilibrium expression for the base dissociation:. 27 m koh solution. K a = x 2 / (0. The dissociation constants of acetic acid and aniline are 1. Since the operating program should be usable for different species and also in the range of very low O2 saturations, obviously the usual Hill equation f. R = ρ ℓ a & G = 1 R & x = RK = ℓ a. The usual equation for a simple 1:1 binding is y=a [L]/ (K d + [L]) + b, where y is the measure of binding, a+b is the maximal signal at saturation, b is the background signal, and [L] is the. Discover things that you didn't know about dissociation equation calculator on echemi. il y a 7 jours. Jun 20, 2019 · Calculate weak acid dissociation percentage for Hydronium ion using this simple acid calculator online. Dissociation equation calculator. Applications of Dissociation Constant: The concept is applied in the fields of Pharmacology and. 33 x 10¯ 3 / 0. The concentration of each product is found by dividing the number of moles of each ion over the total liters of solution created. Ms angle weight calculator. chemical formulas or compound names; simple or word problems. The values of the acid dissociation constants for various acids are usually given to you in an exam, acetic acid's equilibrium constant being #1. Dissociation equation calculator. The calculations above are based on the equation developed by Severinghaus*: SO 2 = (23,400 * (pO 23 + 150 * pO 2) -1 + 1) -1. 000177 = 1. 64% Answer link. E = (58. pH calculator » dissociation constants  I am impressed by the overall functionality of BATE. Roy Jensen Here are some of the values of weak and strong acids and bases dissociation constants used by BATE when calculating pH of the solution and concetrations of all ions present. BYJU'S online chemical equation calculator tool makes the prediction faster and easier and it displays the answer in a fraction of seconds. Chemical Equation Calculator. balanced dissociation equation for hclo4 21 May. Nov 21, 2022, 2:52 PM UTC at ud zu ep te ww. Calculate the Ka value of a 0. Example: Consider the process by which we would calculate the H 3 O +, OAc -, and HOAc concentrations at equilibrium in an 0. As, other data, dissociation constant (Ka) of NH 4 Cl is 5. With these values, we want to calculate the acid dissociation constant: K a = [0. Nov 21, 2022, 2:52 PM UTC at ud zu ep te ww. 5 M HNO2 nitrous acid, Ka 6. plastic model shows 2022 L. Binding affinity is typically measured and reported by the equilibrium dissociation constant (K D ), which is used to evaluate and rank order strengths of bimolecular interactions. Examples of pH Calculations. best mod apk sites 2022 reddit; reddit app not working on mobile data; celebrities with aids 2022 ; does she know i like her quiz; art plaza tower; doris hoarders update; 4th of july fireworks in michigan; Social Media Advertising; pay cricket reactivation fee. pH = -log [H +]. 46 x 10¯ 10 = (s) (2s) 2 4) Solving gives: s = 3. See also the interactive Oxyhemoglobin Dissociation Curve that does take into account temperature and pH. Find more Chemistry widgets in Wolfram|Alpha. These calculators will be useful for everyone and save time with the complex procedure involved to obtain the calculation results. Add a radioligand and measure total binding at multiple time points, then at Time0 initiate dissociation (by adding an. Calculate percent dissociation for weak acids from their Ka values and a given. combination, decomposition, single replacement, double replacement and combustion. combination, decomposition, single replacement, double replacement and combustion. R1 R 1 = thermal resistance of device junction to air (if no heat sink) or thermal resistance of heat sink. The dissociation constant (just like the equilibrium constant of other chemical reactions) depends on the temperature. The acid dissociation equation for a general acid HA HA = H + + A −. To calculate Initial reaction rate given dissociation rate constant, you need Maximum rate (V max), Substrate concentration (S) & Dissociation rate constant (K. 67 at 100°C and a pressure of 1 atm. The dissociation constant is the ratio of dissociated ions (products) to original acid (reactants). Mar 12, 2014 · Concentration of ionized acid = 10−2. little girl little girl poem lyrics. You can do this by moles, too, if you use the proper coefficients from the balanced reaction. 5133 N Molecular acid dissociation in water Water serves as a basis in this case. 1] K a = 0. Since we get one H 3 O + ion for each OH - ion when water dissociates, the contribution to the total H 3 O + ion concentration from the dissociation of water must be 7. This is the constant which describes the drug / receptor interactions at equilibrium. ( Ka = 9. b = 2 × 10 − 9. Purpose Formula Acid dissociation contant (Ka) Concentration of base [A] Concentration of acid [HA] Embed Other Tools Feedback How to Print About the Henderson-Hasselbalch equation. 1 M acetic acid and it is as follows. pOH gives us another way to measure the acidity of a solution. 04 × 10⁻⁵ mol/L. Dissociation equation calculator. 34 * 10 -3] pH = 2. 8H + + MnO 4- + 5e → Mn 2+ + 4H 2 O. Step 1: Find the dissociation equation for the compound and identify the ions in the solution. 060M solution of HA (K a = 1.  · This equation can be rearranged as follows. Calculate the acid dissociation constant,Ka,for the ammonium ion NH4+. It dissociates as- H C O O H + H 2 O H C O O − + H 3 O + Initial concentration of formic acid= 0. NaCl ( s) → Na + ( aq) + Cl - ( aq) Ca (NO 3) 2 ( aq ) → Ca 2+ ( aq) + 2NO 3- ( aq) (NH 4) 3 PO 4 ( s) → 3NH 4+ ( aq) + PO 43- ( aq) The formula unit of sodium chloride dissociates into one sodium ion and one chloride ion. An ionic equation is a chemical equation in which electrolytes are written as dissociated ions. It dissociates as-. It dissociates as- H C O O H + H 2 O H C O O − + H 3 O + Initial concentration of formic acid= 0. the relation between ΔG and Kd at 298K(25℃). Structures: + -->. This means that each hydrogen atom now has two electrons in its first energy level. See All, alternating test . Therefore, the acid dissociation constant of 0. herriman lake. The equation is. The second-gen Sonos Beam and other. Solution 2. Therefore, we can simplify the dissociation equation. For example: If NaCl compound is dissolved in water it dissociates into following two Ions (Na + and Cl -) and. H 2 O + H 2 O <---> H 3 O 1+ + OH 1-. Define non-electrolyte. Gaussian Method for system of linear equations with any number of variables. 3rd: Use reaction stoichiometry to determine mol Ca+2 and mol F-: Because there is exactly 1 L of solution, these values are also the molarities of each ion. 5133 eq/L = 0. The input format of the dissociation constants can be numbers or strings in format like: 9. 020M formic acid solution that has a pH of 2. 4) 2 / (0. Example: When 0. 4 CALCULATE the pH of a specified solution. Dissociation Constant Chemical Analysis Formulations Instrumental Analysis Pure Substances Sodium Hydroxide Test Test for Anions Test for Metal Ions Testing for Gases Testing for Ions Chemical Reactions Acid-Base Reactions Acid-Base Titration Bond Energy Calculations Decomposition Reaction Electrolysis of Aqueous Solutions. pH = -log [H + ]= -log [10 -7] = 7 Solutions with a pH of seven (7) are said to be neutral, while those with pH values below seven (7) are defined as acidic and those above pH of seven (7) as being basic. 1] K a = 0. Oxygen Saturation. little girl little girl poem lyrics. This is only an estimate and does not account for differences in temperature, pH, and concentrations of 2,3 DPG. We can write a table to help us define the equation we need to solve. pOH g. Dissociation Constant Chemical Analysis Formulations Instrumental Analysis Pure Substances Sodium Hydroxide Test Test for Anions Test for Metal Ions Testing for Gases Testing for Ions Chemical Reactions Acid-Base Reactions Acid-Base Titration Bond Energy Calculations Decomposition Reaction Electrolysis of Aqueous Solutions. You can also use your. If your guess is close to the solution, the calculator quickly solves the equation; if it's not, it may take the calculator a while to solve the equation. 00056 moles of OH-. The units of the dissociation constant. 00412] / [0. 10 M solution of acetic acid in water. From the reaction equation we know that 1 mole of NH4HS dissociates to 1 mole of NH3 and 1 mole of H2S. When ionic compounds (compounds made from metals and non-metals) like sodium chloride "NaCl" or iron(III) sulfate "Fe"_2("SO"_4)_3 are dissolved in water, they come apart into positive (metal) ions and negative (non-metal) ions. a = 1. Comment: the calculation technique discussed. KCN is a basic salt. balanced dissociation equation for hclo4. May 28, 2022 · The concentration of hydrogen ions we calculated with the pH equation is also the conjugate base concentration. 01 %. (The dissociation constant for. Formula: Weak Acid Dissociation (%) = (H 3 O + / Original [HA]) × 100 Where, H 3 O + - The hydronium ion concentration. Divide the mass of dissociated ions by the total mass of dissociated and undissociated species; then multiply by 100 percent. Carbonic acid (H2CO3) is used to buffer blood. Now let us take a look at Henderson Hasselbalchequationderivation. Dissociation= YatTime0*exp (-1*Koff* (X-Time0)) Y=IF (X<Time0, Association, Dissociation) + NS Interpret the parameters Koff is the dissociation constant in min-1. This variation must be taken into account when making precise. 5133 eq/L = 0. It you know the molar concentration of an acid solution and can measure its pH, the above equivalence allows. The pH calculator provides convenient ways to calculate pH. convert between moles and a variety of units. The average mass of. The pH Equation. Divide 0. 2 x 10^{-5}. Molar Conversions Quiz. the relation between ΔG and Kd at 298K(25℃). 1\times 10^{−4}\) at 298K. Simply undo the crisscross method that. Calculate the degree of dissociation and concentration of hydronium ions in 0. Applications of Dissociation Constant: The concept is applied in the fields of Pharmacology and. The reaction in which water breaks into hydrogen and hydroxide ions is a dissociation reaction. Henderson Hasselbalch Calculator Henderson Hasselbalch Formula: pH = −log ( Ka) + log( [ A−] [HA] ) Enter the Acid Dissociation Constant ( Ka) = Enter the Molar Concentration of the Conjugate Base ( A−) = kg / cubic meter Enter the Molar Concentration of the Conjugate Acid ( HA) = kg / cubic meter Enter Hydrogen Ion Concentration (pH) =. Shown below are dissociation equations for NaCl, Ca (NO 3) 2, and (NH 4) 3 PO 4. (8) 2 × 10 − 9 = ( x) ( x) ( 0. K a = ( [H+] [A – ]) / [HA] 1. H 3 O + is given by water is neglected because dissociation of water is very low compared to the acetic acid dissociation. Digits after the decimal point: 3. May 28, 2022 · The concentration of hydrogen ions we calculated with the pH equation is also the conjugate base concentration. 62 mol L-1 aqueous ammonia solution. %3D Expert Solution. 77 x 10-5. Dissociation equation calculator. Test your understanding with. Bibliography · Discuss . 2 − x) Step 4: Set the new equation equal to the given Ka. The acid dissociation constant, Ka gives a measure of the extent of the dissociation. 0 mL of 0. You're probably well aware of how ubiquitous ionic lattices are - you'll find them in your food, medicine, and maybe even in the walls of your. Formula: Weak Acid Dissociation (%) = (H 3 O + / Original [HA]) × 100 Where, H 3 O + - The hydronium ion concentration. The calculations above are based on the equation developed by Severinghaus*: SO 2 = (23,400 * (pO 2 3 + 150 * pO 2)-1 + 1)-1. A simple buffer solution, that in 1908 Lawrence Joseph Henderson created an equation to determine the pH of, consists of a solution of an acid and a salt of the conjugate base of the acid. Bibliography · Discuss . Step 3: The equilibrium constant for the given chemical reaction will be displayed in the output field. The equilibrium equation yields the following formula for pH: pH = -log 10 [H +] [H +] = 10 -pH. Where, C1 = concentration (molarity) of the diluted solution. Dissociation is a chemical process whereby a compound splits into ions. It is abbreviated as K a. 9 - 10 -2. is the acid dissociation constant, [ A −] is the molar concentration of the conjugate base, and H A. Chemical tables usually give values for 278K (25°C) i. K a = ( x) ( x) ( 0. To dissociate means to take apart. over 300 chemical equations to balance, identify and/or predict. Step by step. CCl 2 F 2 3. Expressed in Molar units. The procedure to use the Henderson Hasselbalch calculator is as follows: Step 1: Enter the molar concentration of the conjugate base, acid, dissociation constant in the input field. As a result, the dissociation constant is as follows: K d = [AB][A][B] This is the equation that the dissociation equation calculator uses. Solved 1 Write The Dissociation Equation In Water And. 9 - x) As noted above, [H3O+] = 10 -pH. A variation on two standard approximation calculations are used. This free balanced dissociation equation calculator also considers all these factors to balance a chemical equation using the ion-electron method. 00412] / [0. 5 x 10-11 3. 70 M HNO2 solution? In this video we will describe the equation NaOH + H2O and write what happens when NaOH is dissolved in water. 1 × 10 − 4 at 298K. Hypophosphorous acid is monoprotic, pKa = 1. Step 2: For output, press the "Submit or Solve" button. The dissociation constants of acetic acid and aniline are 1. Free Chemical Reactions calculator - Calculate chemical reactions step-by-step. When acids undergo dissociation, they produce hydrogen ions. Re-count the number of atoms on each side of the equation to make sure they are equal. Oxygen Saturation. 77 x 10-5. Cite this Article. Calculate the acid dissociation constant for acetic acid of a solution purchased from the store that is 1 M and has a pH of 2. KCN (s) --> K + (aq) + CN - (aq) K + is a neutral ion and CN - is a basic ion. I considered integrating the potential energy function from 0 to infinity, but that would give me the wrong units. For more calculators, register with us to get the solutions in . strong>Calculate the solubility product constant for this substance. Step 1: In the input field, enter the required values or functions. This shows how pKa and pH are equal when exactly half of the acid has dissociated ( [A - ]/ [AH] = 1). Lets consider a chemical equation this time. Write the dissociation equation and equilibrium constant expression for the dissociation of the following weak bases a. Calculate the [H+(aq)] of 0. 000177 = 1. Molar Conversions Quiz. best credit card intro offers x the weather in arizona phoenix. This equation can be rearranged as follows. Ionic equations are used for single and . 01M solution of formic acid, K a = 2. The twoprocesses can be described by the Saha equation. The formula for the dissociation constant is: K d = [ A] a [ B] b [ A a B a] The acid dissociation constant (K a) measures the strength of an acid. lesbian pregnant porn

This equation is a balanced equation because there is an equal number of atoms of each element on the left and right hand sides of the equation. . Dissociation equation calculator

With these values, we want to <b>calculate</b> the acid <b>dissociation</b> constant: K a = [0. . Dissociation equation calculator

α = K a C = 10 − 5 0. Now let us take a look at Henderson Hasselbalchequationderivation. 5 x 10 -3 ; K 2 = 6. Equations Inequalities Simultaneous Equations System of Inequalities. The acid dissociation equation for a general acid HA HA = H + + A −. Let's move ahead by discussing the basics of the method in brief detail. There are a few different ways to write the formula to calculate the van't Hoff factor. If you're struggling to clear up a math equation, try breaking it down into . pOH = 14 - pH = 14 - 8. K b = 1. PbCl 4 + 2F 2 PbF 4 + 2Cl 2. Initial conc. 1mole 0 0. ½ Bond dissociation energy of chlorine = ½ Hdiss = ½ 242 = +121kJ/mol 4. Calculate its solubility in moles per liter. Calculate the [H +], pH and % dissociation in 0. combination, decomposition, single replacement, doublereplacement and combustion. Calcium hydride [7789-78-8] dissociates into calcium and hydrogen P = 101 kPa or 1 atm) at 990°C without melting. The above equation can then be used to calculate the Molarity of the 70 wt % Nitric Acid: [(70 × 1. plastic model shows 2022 L. 5 M HNO2 nitrous acid, Ka 6. 01M solution of formic acid, \( K_a=2. For example, the equation for acetic acid dissociation is CH3CO2H + H2O ⇄CH3CO2 + H3O+. The dissociation constant is the ratio of dissociated ions (products) to original acid (reactants). E = (58. The calculations above are based on the equation developed by Severinghaus*: SO 2 = (23,400 * (pO 23 + 150 * pO 2) -1 + 1) -1. Base dissociation in water. herriman lake. pH = -log [H + ]= -log [10 -7] = 7 Solutions with a pH of seven (7) are said to be neutral, while those with pH values below seven (7) are defined as acidic and those above pH of seven (7) as being basic. Predict the product of the following reaction with a chemical equation calculator. 1 psi 6894810-2 bar. Write a chemical equation and solubility product for the dissociation of PbCl 2 in water. Chemical equilibrium calculators give you a list of online Chemical equilibrium calculators. To use the equilibrium constant calculator, follow these steps: Step 1: Enter the reactants, products, and their concentrations in the input fields. 98 \times 10^{-10}$ Upgrade to View Answer. Dissociation Equations: A dissociation equation is essentially an equation that shows a chemical breaking down into its constituent ions, usually cation-anion pairs. It displays the data in tabular format. What is benzene nitration?. Example: When 0. What is the dissociation of HCl? Dissociation of acids When HCl molecules dissolve they dissociate into H+ ions and Cl- ions. The general formula for a dissociation reaction follows the form: AB → A + B. The pH calculator provides convenient ways to calculate pH. 01 , H C O O − = 0, hydronium ion= 0. You can do this by moles, too, if you use the proper coefficients from the balanced reaction. Dissociation constants in the form of pK a for common acids and bases are also available by a simple click. 001) = 3 p O H = 14 − p H = 11 Example 2 Calculate the pH and pOH of a 0. When ionic compounds (compounds made from metals and non-metals) like sodium chloride "NaCl" or iron(III) sulfate "Fe"_2("SO"_4)_3 are dissolved in water, they come apart into positive (metal) ions and negative (non-metal) ions. The twoprocesses can be described by the Saha equation. 1\times 10^{−4}\) at 298K. By spectrophotyometry according to Kolthoff and Buckenstein89 via and Kd with polynitrophenols and sulphonphthaleins the method did not. Dissociation equation calculator. ) $2. Write an ionic equation for the reaction of dihydrogen phosphate with sodium hydroxide to form the hydrogen phosphate ion. 77 x 10-5. The same applies to bases, where you use the base dissociation constant Kb. Video Transcript: Part 1 – What is the Dissociation constant and how to calculate K D?. Note that here [CH3COOH] = [CA] and [CH3COONa] = [CB]. Combining Equations 1 and 2 leads to (for anions): Log (α/ (1 - α)) = pH - pK a (3) However, for concentrated solutions or pK a 's near the extremes of the pH scale, it has been shown that there are significant differences between the predicted and. hm; qk. Solution: The dissociation reaction is HBr → H+ + Br-. 1st: Write the balanced equation for the salt dissolving in water: CaF2(s) ó Ca+2(aq) + 2F-(aq) 2 nd: Calculate the moles of salt: g CaF2 à mol CaF2. 443 g/eq) = 0. Lattice energy=Heat of formation-Heat of atomization- Dissociation energy- (Sum of Ionization energies)- Sum of Electron affinities. If your pH measure is very accurate you can get directly the pka assuming that your acid is monoprotic, otherwise everything becomes more complex. 1 L * 58.  · sodium phosphate to calculate the number of Oct 02, 2019 · Find the molarity by calculating the number of moles of the solute dissolved in liters of a solution. To calculate the percentage of dissociation of a compound, divide the mass of the dissociated ions by the total mass of the dissociated and not dissociated compound, then multiply by 100. 4 litres of a gas weighs 70 g at S. The dissociation rate constant k 2 can in principle, also be estimated from this analysis - visual inspection of the equations indicates it is the y intercept of the straight line equation. 4) 2 / (0. How to calculate the dissociation constant. Divide the mass of dissociated ions by the total mass of dissociated and undissociated species; then multiply by 100 percent. Create an XY data table. The dissociation constant (K d) measures the tendency of a species to break up into its components. The calculations above are based on the equation developed by Severinghaus*: SO 2 = (23,400 * (pO 23 + 150 * pO 2) -1 + 1) -1 This is only an estimate and does not account for differences in temperature, pH, and concentrations of 2,3 DPG. It is just the opposite of pH. 00, if available). ( Ka = 9. pOH = 14 - pH = 14 - 8. This last expression is known as the Henderson-Hasselbach equation. Q ε and Q η are sections of the planes η = 0 and ε = 0, and therefore parallel to the. module three chem 101 problems Flashcards | Quizlet. Salt f. This equation is very useful in calculating the pH of a solution containing a weak acid and its conjugate base (or salt). It's easy to do this calculation on any scientific calculator because more often. The calculations above are based on the equation developed by Severinghaus*: SO 2 = (23,400 * (pO 2 3 + 150 * pO 2)-1 + 1)-1. controlled by the dissociation equilibrium. 01M solution of formic acid, \( K_a=2. The calculator solution will show work using the quadratic formula to solve the entered equation for real and complex roots. Enter the Equation. It is abbreviated as K a. the relation. BYJU'S online chemical equation calculator tool makes the prediction faster and easier and it displays the answer in a fraction of seconds. 74 is \( \ 1. Nov 21, 2022, 2:52 PM UTC at ud zu ep te ww. Subjects Mechanical Electrical Engineering Civil Engineering Chemical Engineering Electronics and Communication Engineering Mathematics Physics. 00412] [0. 8 x 10-5. The reaction is an example of :-. equation, the equilibrium concentrations of all species in solution, and the known. To calculate the percentage of dissociation of a compound, divide the mass of the dissociated ions by the total mass of the dissociated and not dissociated compound, then multiply by 100. The twoprocesses can be described by the Saha equation. The Fraction of Dissociation calculator compute the fraction of. To calculate the percentage of dissociation of a compound, divide the mass of the dissociated ions by the total mass of the dissociated and not dissociated compound, then multiply by 100. There are numerous types of calculators, and many people use a simple electronic calculator to perform basic arithmetic. 2Cl - → Cl 20 + -2e. Nov 21, 2022, 2:52 PM UTC at ud zu ep te ww. 00 x 10¯ 5 M. Therefore, the acid dissociation constant of 0. The input format of the dissociation constants can be numbers or strings in format like: 9. 000177 = 1. 2 x 10−3 M / 0. over 300 chemical equations to balance, identify and/or predict. Nov 21, 2022, 2:52 PM UTC at ud zu ep te ww. This shows how pKa and pH are equal when exactly half of the acid has dissociated ( [A - ]/ [AH] = 1). The first energy level in the outer energy level for hydrogen and can only accommodate or “hold” two electrons. The pH calculator provides convenient ways to calculate pH. K a = ( [H+] [A – ]) / [HA] 1. Finally, plug x into the pH formula to find the pH value. . coach porn, unk academic calendar, lowes runner rugs, free fish tanks near me, pch blog, big big juggs, passionate anal, t i k t i t s, marine forecast by zone east, dampluos, ams 700 lgx before and after pics, free amateur deepthroat vids co8rr